Saturday, December 20, 2014

Very interesting Hypothesis - Mars, Ancient Water, Deep Hydrogen, and Life

We have entered into the hydrogen market and I am very interested in the fact that a few months later we start seeing headlines like this. We did not plan it this way but I have to say after 25 some years in the industry I do start to see patterns and many technologies have been around for years. Hydrogen is one of those and I felt the timing was right. To me it is a no brainer. I witnessed hydrogen produced from a solar panel and water years ago. It is a clean burning fuel that can be created at the location needed for use. I have heard all the economic detractors and think they are missing the whole picture. I said this about solar 25 years ago and I am saying this about hydrogen now. I have utilized batteries in many applications over the years and am intimately knowledgeable on their limitations. I predict they will have a 10 year run. When solar really got traction in the market there were numerous solar technologies that jumped up taking in huge investments. All these thin film solar companies are pretty much gone or forgotten. The fact is what was tried and true (silicon) is what is primarily used and if you want to make a bet on solar panels it is primarily how to reduce the cost of making the solar cells. Folks I offer the hypothesis that energy storage will follow the same pattern. We know that hydrogen is a great energy storage method and offers versatility that batteries can never achieve. It has been used for many years (ask NASA) or the hydro dams in Canada that have been producing hydrogen from their excess power using electrolysis and water for many years now. It will be the reduction in cost and enhancing the efficiency. We did it with silicon and we can do it with hydrogen. I am pretty proud that we have engineered a unit that has enhanced the efficiency and eliminated the need to scrub the hydrogen from the oxygen but the fact is that when it gains traction like solar has these young emerging minds will continue to innovate and perfect the technology.
Scientific American
By Caleb A. Scharf 



Two billion year-old water pockets and a revised deep hydrogen content are good news for Earth’s vast subsurface biosphere, and could offer clues to life on Mars and much further beyond.


Excitement over the Curiosity rover’s recently reported detection  of a ‘spike’ in localized atmospheric methane – persisting over a couple of months – is well founded. It’s possible that this represents a very real clue to past or present life on Mars. Or rather, life in Mars.
The great majority of methane that we find here on Earth (whether in the air or in subsurface deposits) has a biological origin, clearly marked by the preference biological systems have for lighter isotopes – carbon-12 over carbon-13 for example. This methane is generated by methanogenesis, a metabolic process that seems to be confined to members of the domain of single-celled organisms called the Archaea.

There’s more than one chemical pathway for making methane, but the most obvious is the combination of carbon dioxide with molecular hydrogen, and that’s precisely the reaction that a slew of methanogenic archaea latch onto. Molecular hydrogen is a potent source of chemical energy, and other organisms such as sulfate-reducing bacteria also gobble it up. So where do they find that hydrogen?

One source is where rock and water sit together. Radioactivity from rocks laced with elements like uranium can break up water molecules (the process of radiolysis), and the geochemical process of serpentization  also spits out molecular hydrogen in abundance. Active hydrothermal vent systems on ocean beds are one environment where hydrogen is readily made, and methanogenic organisms thrive there. But what about the subsurfaces of Earth’s continents, the most ancient parts of the lithosphere?
Recent discoveries of isolated pockets of highly saline water at extraordinary depths of 1-2 miles in South African and Canadian mines have revealed these reservoirs to be tens of millions to billions of years old – the current record holder  having formed somewhere between 1.5 and 2.6 billion years ago. Places like these are, in relative terms, packed with chemical energy that life can exploit, and does . Except it’s not been clear that extrapolating the local production of molecular hydrogen in such reservoirs to a global total yields anything worth getting excited about.
Now a new study by Lollar, Onstott, Lacrampe-Couloume, & Ballentine reported inNature , suggests that the deep (5km) continental zones could indeed be a major producer of hydrogen. Specifically, the most ancient Precambrian continental subsurface (rock older than about 540 million years), could generate molecular hydrogen at a rate 40 to 250 times higher than previously thought – a production on par with that associated with the much younger marine lithosphere. This Precambrian material exists in about 70% of the Earth’s continental area, and could contain as much water as all surface rivers, swamps, and lakes.
The conclusion is that the global production of molecular hydrogen needs an upward revision and, most critically, at least half of that is coming from the deep, ancient continental subsurface – which is not dry, not inert, and seems to be filled with life.

Connecting these discoveries to methane on Mars is, at present, a stretch. But it’s not unreasonable to suppose that the ancient martian subsurface could resemble Earth’s present Precambrian subsurface environment – with long undisturbed water sitting in fractures, and a healthy molecular hydrogen production. Extinct or extant life, however it operated, would surely exploit an energy source like this, and the products could eventually find their way to the surface.
If time, power, and the luck of another methane spike allows Curiosity to examine the isotopic ratios in the gas, we might get a critical hint of any biochemical origins – with a ready explanation on hand from our very own planetary depths.
On a far grander scale, the idea of purely geophysical ‘habitability’ in distant exoplanets – biospheres only ever driven by the inner workings of a world, without surface life – is an important one. It may be the height of conceit to imagine that the externally visible biosphere of the Earth is a template for the majority of life in the universe.
Figuring out how detectable signatures of troglodytic life could bubble up from below would go a long way in encouraging us to target worlds that we might otherwise ignore. So too would a better understanding of molecular hydrogen generation in a planetary crust, where the original ingredients of a world – from the elemental mix to the availability of radioactive nuclei  – are set by still deeper cosmic rhythms of stellar life and death.
Traces of methane on Mars, and deep hydrogen on Earth may seem remote and tenuous, but the implications could be enormous.
Caleb A. ScharfAbout the Author: Caleb Scharf is the director of Columbia University's multidisciplinary Astrobiology Center. He has worked in the fields of observational cosmology, X-ray astronomy, and more recently exoplanetary science. His books include Gravity's Engines (2012) and The Copernicus Complex (2014) (both from Scientific American / Farrar, Straus and Giroux.) Follow on Twitter @caleb_scharf .

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